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Decoration of CdMoO micron polyhedron with Pt nanoparticle and their enhanced photocatalytic performance

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 12, Pages 1949-1961 doi: 10.1007/s11705-023-2360-6

Abstract: This study aimed to prepare and apply a novel Pt/CdMoO4sub> composite photocatalyst for photocatalyticThe Pt/CdMoO4sub> composite was subjected to comprehensive investigation on the morphology, structureThe results demonstrate the dispersion of Pt nanoparticles on the CdMoO4sub> surface.Close contact between CdMoO4sub> and Pt was observed, resulting in the formation of a heterojunctionwork function value than CdMoO4sub>, resulting in electron drift from CdMoO4sub> to Pt

Keywords： photocatalytic N2sub> fixation Pt/CdMoO4sub> tetracycline degradation Schottky barrier

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Highly selective catalytic hydrodeoxygenation of guaiacol to cyclohexane over Pt/TiO

Zhong HE,Xianqin WANG

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 3, Pages 369-377 doi: 10.1007/s11705-014-1435-9

Abstract: Catalysts Pt/TiO and NiMo/Al O are highly active and selective for the hydrodeoxygenation of guaiacolNiMo/Al O and Pt/Al O are more active and selective for cyclohexane formation as compared with Pt/TiOat 285 °C and 4 MPa.However, Pt/TiO is stable while the other two catalysts deactivate due to the nature and amount of coke

Keywords： Pt/TiO2sub> NiMo/Al2sub>O3sub> Pt/Al2sub>O3sub> bio-oil hydrodeoxygenation

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The effect of preparation conditions of Pt/Al

Lei YUAN, Xiang ZHENG, Kaijiao DUAN, Hao HU, Jinggang WANG, Seong Ihl WOO, Zhiming LIU

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 3, Pages 457-463 doi: 10.1007/s11783-013-0512-5

Abstract: Selective catalytic reduction of NO by H in the presence of oxygen has been investigated over Pt/AlThe higher surface area and the presence of metallic Pt over Pt/Al O pre-treated by H or pretreated

Keywords： NOxsub> reduction Pt/Al2sub>O3sub> preparation condition H2sub>-SCR

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Investigation of fluorescence characterization and electrochemical behavior on the catalysts of nanosized Pt-Rh

Chang-Mao HUNG, Wen-Liang LAI, Jane-Li LIN

Frontiers of Environmental Science & Engineering 2013, Volume 7, Issue 3, Pages 428-434 doi: 10.1007/s11783-013-0517-0

Abstract: nitrogen at temperatures range from 423K to 673K by selective catalytic oxidation (SCO) over a nanosized Pt-RhThe results demonstrated that at a temperature of 673K and an oxygen content of 4%, approximately 99%of the NH was removed by catalytic oxidation over the nanosized Pt-Rh/γ-Al O catalyst.Therefore, the application of nanosized Pt-Rh/γ-Al O catalyst can significantly enhance the catalyticclusters in intrinsic emission from nanosized Pt-Rh/γ-Al O catalyst.

Keywords： ammonia (NH3sub>) nanosized Pt-Rh/γ-Al2sub>O3sub> catalyst excitation-emission fluorescent

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Efficient synthesis of titania nanotubes and enhanced photoresponse of Pt decorated TiO

Yuxin YIN, Xin TAN, Feng HOU, Lin ZHAO

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 3, Pages 298-304 doi: 10.1007/s11705-009-0019-6

Abstract: Furthermore, Pt nanoparticles were successfully deposited on the surface of TiO nanotubes by ac electrodepositionThe TiO /Pt composites were characterized by field emission scanning electron microscope (FESEM), X-rayAn enhancement in photocurrent density has been achieved upon modification of TiO nanotubes with Pt

Keywords： TiO2sub> nanotube arrays HMT TiO2sub>/Pt Photocurrent density

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Evaluation of H2sub> on the Evolution Mechanism of NOxsub> Storage and Reductionover Pt–Ba–Ce/γ-Al2sub>O3sub> Catalysts Article

Pan Wang, Jing Yi, Chuan Sun, Peng Luo, Lili Lei

Engineering 2019, Volume 5, Issue 3, Pages 568-575 doi: 10.1016/j.eng.2019.02.005

Abstract:

In this investigation, Pt–Ba–Ce/γ-Al2sub>O3sub> catalysts were preparedThe physical and chemical properties of the Pt–Ba–Ce/γ-Al2sub>O3sub>>xsub>, CeO2sub>, and BaCO3sub>, whose peaks were observed in X-ray diffractiontransmission electron microscope (TEM), and that the difference between Ce³⁺ and Ce^{4+>catsub> at 350 °C, which was ascribed to the increase in NO2sub> yield.}

Keywords： Pt–Ba–Ce/γ-Al2sub>O3sub> catalysts Physicochemical properties NOxsub> storageand reduction NOxsub> emission H2sub> reductant

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ZnFe2sub>O4sub>/BiVO4sub> Z-scheme heterojunction for efficient visible-light photocatalytic

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11, Pages 1728-1740 doi: 10.1007/s11705-023-2322-z

Abstract: A novel Z-scheme ZnFe2sub>O4sub>/BiVO4sub> heterojunction photocatalyst was successfullyCompared with the single-phase counterparts, ZnFe2sub>O4sub>/BiVO4sub> demonstratedConsequently, the 30% ZnFe2sub>O4sub>/BiVO4sub> catalyst afforded a degradation>4sub>-based catalysts.Moreover, the as-synthesized ZnFe2sub>O4sub>/BiVO4sub> heterojunctions were quite

Keywords： ZnFe2sub>O4sub>/BiVO4sub> Z-scheme heterojunction photocatalytic degradation

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Li4sub>SiO4sub>-coated LiNi0.5sub>Mn1.5sub>O4sub> as the high performance

Shifeng YANG, Wenfeng REN, Jian CHEN

Frontiers in Energy 2017, Volume 11, Issue 3, Pages 374-382 doi: 10.1007/s11708-017-0494-2

Abstract: The preparation of Li SiO -coated LiNi Mn O materials by sintering the SiO -coated nickel-manganese oxides with lithium salts using abundant and low-cost sodium silicate as the silicon source was reported. The samples were characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. It was found that a uniform and complete SiO coating layer could be obtained at a suitable pH value of 10, which transformed to a good Li SiO coating layer afterwards. When used as the cathode materials for lithium-ion batteries, the Li SiO -coated LiNi Mn O samples deliver a better electrochemical performance in terms of the discharge capacity, rate capability, and cycling stability than that of the pristine material. It can still deliver 111.1 mAh/g at 20 C after 300 cycles, with a retention ratio of 93.1% of the stable capacity, which is far beyond that of the pristine material (101.3 mAh/g, 85.6%).

Keywords： lithium-ion batteries cathode material LiNi0.5sub>Mn1.5sub>O4sub> lithium-ion conductor

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Rh2sub>O3sub>/hexagonal CePO4sub> nanocatalysts for N2sub>O decomposition

Huan Liu, Zhen Ma

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4, Pages 586-593 doi: 10.1007/s11705-017-1659-6

Abstract: Hexagonal CePO nanorods were prepared by a precipitation method and hexagonal CePO nanowires were prepared by hydrothermal synthesis at 150 °C. Rh(NO ) was then used as a precursor for the impregnation of Rh O onto these CePO materials. The Rh O supported on the CePO nanowires was much more active for the catalytic decomposition of N O than the Rh O supported on CePO nanorods. The stability of both catalysts as a function of time on stream was studied and the influence of the co-feed (CO , O , H O or O /H O) on the N O decomposition was also investigated. The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron microscopy, hydrogen temperature-programmed reduction, oxygen temperature-programmed desorption, and CO temperature-programmed desorption in order to correlate the physicochemical and catalytic properties.

Keywords： Rh2sub>O3sub> CePO4sub> N2sub>O decomposition

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acid anions on highly efficient Ce-based catalysts for selective catalytic reduction of NO with NH3sub>

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10, Pages 1399-1411 doi: 10.1007/s11705-023-2345-5

Abstract: Three kinds of Ce-based catalysts (CePO4sub>, CeVO4sub>, Ce2sub>(SO4sub>)The catalytic efficiencies of the three catalysts are as follow: CePO4sub> > CeVO4sub>The effect of PO4sub>^3–, VO4sub>^3– and SO4sub>^{2–sub>4sub> and CeVO4sub> catalysts also exhibited relatively strong tolerance of>2sub> for Ce2sub>(SO4sub>)3sub>.}

Keywords： CePO4sub> CeVO4sub> Ce2sub>(SO4sub>)3sub> selective catalytic reduction

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ZnFe2sub>O4sub> deposited on BiOCl with exposed (001) and (010) facets for photocatalyticreduction of CO2sub> in cyclohexanol

Guixian Song, Xionggang Wu, Feng Xin, Xiaohong Yin

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 2, Pages 197-204 doi: 10.1007/s11705-016-1606-y

Abstract: ZnFe O -BiOCl composites were prepared by both hydrothermal and direct precipitation processes and the structures and properties of the samples were characterized by various instrumental techniques. The samples were then used as catalysts for the photocatalytic reduction of CO in cyclohexanol under ultraviolet irradiation to give cyclohexanone (CH) and cyclohexyl formate (CF). The photocatalytic CO reduction activities over the hydrothermally prepared ZnFe O -BiOCl composites were higher than those over the directly-precipitated composites. This is because compared to the direct-precipitation sample, the ZnFe O nanoparticles in the hydrothermal sample were smaller and more uniformly distributed on the surface of BiOCl and so more heterojunctions were formed. Higher CF and CH yields were obtained for the pure BiOCl and BiOCl composite samples with more exposed (001) facets than for the samples with more exposed (010) facets. This is due to the higher density of oxygen atoms in the exposed (001) facets, which creates more oxygen vacancies, and thereby improves the separation efficiency of the electron-hole pairs. More importantly, irradiation of the (001) facets with ultraviolet light produces photo-generated electrons which is helpful for the reduction of CO to ·CO . The mechanism for the photocatalytic reduction of CO in cyclohexanol over ZnFe O -BiOCl composites with exposed (001) facets involves electron transfer and carbon radical formation.

Keywords： reduction of CO2sub> cyclohexanol ZnFe2sub>O4sub> deposited BiOCl facet composite

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Complete oxidation of methane on CoO-SnO catalysts

Xingfu TANG , Jiming HAO , Junhua LI ,

Frontiers of Environmental Science & Engineering 2009, Volume 3, Issue 3, Pages 265-270 doi: 10.1007/s11783-009-0019-2

Abstract: CoO-SnO hybrid oxides were prepared by the coprecipitation method and were used to oxidate methane (CH) in presence of oxygen. The CoO-SnO with a molar ratio of Co/(Co+Sn) at 0.75 exhibited the highest catalytic activity among all the CoO-SnO hybrid oxides. Experimental results showed that the catalysts were considerably stable in the CH combustion reaction, and were verified by X-ray photoelectron spectra (XPS). It was found that CoO was the active species, and SnO acted as a support or a promoting component in the CoO-SnO hybrid oxides. The surface area was not a major factor that affected catalytic activity. The hydrogen temperature-programmed reduction (H-TPR) results demonstrated that the interaction between cobalt and tin oxides accelerated the mobility of oxygen species of CoO-SnO, leading to higher catalytic activity.

Keywords： Co3sub>O4sub>-SnO2sub> complete oxidation methane (CH4sub>)

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On the monolayer dispersion behavior of Co3sub>O4sub> on HZSM-5 support: designing applicable

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11, Pages 1741-1754 doi: 10.1007/s11705-023-2332-x

Abstract: Based on monolayer dispersion theory, Co3sub>O4sub>/ZSM-5 catalysts with different loadingsCo3sub>O4sub> can spontaneously disperse on HZSM-5 support with a monolayer dispersionBelow the monolayer dispersion threshold, Co3sub>O4sub> is finely dispersed as sub-monolayersreaction performance. 4% Co3sub>O4sub>/ZSM-5, the catalyst close to the monolayer dispersioncapacity amount of Co3sub>O4sub> onto HZSM-5 support.

Keywords： Co3sub>O4sub>/ZSM-5 NOxsub>-SCR by NH3sub> monolayer dispersionthreshold effect surface acid sites surface active O2sub>^– anions

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Effects of Pd doping on N

Mingxin Dong, Jun Wang, Jinxin Zhu, Jianqiang Wang, Wulin Wang, Meiqing Shen

Frontiers of Environmental Science & Engineering 2017, Volume 11, Issue 6, doi: 10.1007/s11783-017-0976-9

Abstract: This present work investigated the effects of Pd doping on N O formation over Pt/BaO/Al O catalyst.Three types of catalysts, Pt/BaO/Al O , Pt/Pd mechanical mixing catalyst (Pt/BaO/Al O +Pd/Al O ) andPt-Pd co-impregnation catalyst (Pt-Pd/BaO/Al O ) were prepared by incipient wetness impregnation methodCompared with Pt/BaO/Al O , (Pt/BaO/Al O +Pd/Al O ) produced less N O and more NH during NO storageand reduction process, while an opposite trend was found over (Pt-Pd/BaO/Al O +Al O ).

Keywords： NOxsub> storage reduction Pt/BaO/Al2sub>O3sub> Pd doping N2sub>O formation

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Thermal and Mechanical Properties Optimization of ABO4sub> Type EuNbO4sub> By the Article

Lin Chen, Jing Feng

Engineering 2020, Volume 6, Issue 2, Pages 177-184 doi: 10.1016/j.eng.2019.12.006

Abstract:

Ferroelastic ABO4sub> type RETaO4sub> and RENbO4sub> ceramics (where>4sub> have been found to be better than those of RENbO4sub>.>4sub> fabricated through a solid-state reaction (SSR).The Young's modulus and the thermal expansion coefficient (TEC) of EuNbO4sub> are effectivelyThe results indicate that the thermal and mechanical properties of EuNbO4sub> can be effectually

Keywords： Thermal barrier coatings Rare earth niobates Substitution Thermal conductivity Thermal expansion coefficients Young’s modulus

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Title Author Date Type Operation

Decoration of CdMoO micron polyhedron with Pt nanoparticle and their enhanced photocatalytic performance

Journal Article

Highly selective catalytic hydrodeoxygenation of guaiacol to cyclohexane over Pt/TiO

Zhong HE,Xianqin WANG

Journal Article

The effect of preparation conditions of Pt/Al

Lei YUAN, Xiang ZHENG, Kaijiao DUAN, Hao HU, Jinggang WANG, Seong Ihl WOO, Zhiming LIU

Journal Article

Investigation of fluorescence characterization and electrochemical behavior on the catalysts of nanosized Pt-Rh

Chang-Mao HUNG, Wen-Liang LAI, Jane-Li LIN

Journal Article

Efficient synthesis of titania nanotubes and enhanced photoresponse of Pt decorated TiO

Yuxin YIN, Xin TAN, Feng HOU, Lin ZHAO

Journal Article

Evaluation of H2sub> on the Evolution Mechanism of NOxsub> Storage and Reductionover Pt–Ba–Ce/γ-Al2sub>O3sub> Catalysts

Pan Wang, Jing Yi, Chuan Sun, Peng Luo, Lili Lei

Journal Article

ZnFe2sub>O4sub>/BiVO4sub> Z-scheme heterojunction for efficient visible-light photocatalytic

Journal Article

Li4sub>SiO4sub>-coated LiNi0.5sub>Mn1.5sub>O4sub> as the high performance

Shifeng YANG, Wenfeng REN, Jian CHEN

Journal Article

Rh2sub>O3sub>/hexagonal CePO4sub> nanocatalysts for N2sub>O decomposition

Huan Liu, Zhen Ma

Journal Article

acid anions on highly efficient Ce-based catalysts for selective catalytic reduction of NO with NH3sub>

Journal Article

ZnFe2sub>O4sub> deposited on BiOCl with exposed (001) and (010) facets for photocatalyticreduction of CO2sub> in cyclohexanol

Guixian Song, Xionggang Wu, Feng Xin, Xiaohong Yin

Journal Article

Complete oxidation of methane on CoO-SnO catalysts

Xingfu TANG , Jiming HAO , Junhua LI ,

Journal Article

On the monolayer dispersion behavior of Co3sub>O4sub> on HZSM-5 support: designing applicable

Journal Article

Effects of Pd doping on N

Mingxin Dong, Jun Wang, Jinxin Zhu, Jianqiang Wang, Wulin Wang, Meiqing Shen

Journal Article

Thermal and Mechanical Properties Optimization of ABO4sub> Type EuNbO4sub> By the

Lin Chen, Jing Feng

Journal Article

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